A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls
Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n (in advance, namely Y/Eu-MOF), is described. The three-dimensional structure...
| Main Authors: | , , , , , , , |
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| Format: | info:eu-repo/semantics/article |
| Language: | English |
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MDPI
2022
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| Subjects: | |
| Online Access: | http://hdl.handle.net/10835/13440 |
| _version_ | 1789406696999747584 |
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| author | Echenique-Errandonea, Estitxu López-Vargas, Mireya E. Pérez, Juana M. Rojas, Sara Choquesillo-Lazarte, Duane Seco, José M. Fernández de las Nieves, Ignacio Rodríguez-Diéguez, Antonio |
| author_facet | Echenique-Errandonea, Estitxu López-Vargas, Mireya E. Pérez, Juana M. Rojas, Sara Choquesillo-Lazarte, Duane Seco, José M. Fernández de las Nieves, Ignacio Rodríguez-Diéguez, Antonio |
| author_sort | Echenique-Errandonea, Estitxu |
| collection | DSpace |
| description | Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n (in advance, namely Y/Eu-MOF), is described. The three-dimensional structure has been synthesized by solvothermal routes and thoroughly characterized, by means of single crystal X-ray diffraction, powder X-ray diffraction, electronic microscopy, ICP-AES, electrophoretic mobility, and FTIR spectra. Intriguingly, the porous nature allows for coordinated solvent molecules displacement, yielding unsaturated metal centers, which can act as a Lewis acid catalyst. This novel supramolecular entity has been tested in cyanosilylation and hydroboration reactions on carbonyl substrates of a diverse nature, exhibiting an extraordinary activity. |
| format | info:eu-repo/semantics/article |
| id | oai:repositorio.ual.es:10835-13440 |
| institution | Universidad de Cuenca |
| language | English |
| publishDate | 2022 |
| publisher | MDPI |
| record_format | dspace |
| spelling | oai:repositorio.ual.es:10835-134402023-04-12T19:48:17Z A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls Echenique-Errandonea, Estitxu López-Vargas, Mireya E. Pérez, Juana M. Rojas, Sara Choquesillo-Lazarte, Duane Seco, José M. Fernández de las Nieves, Ignacio Rodríguez-Diéguez, Antonio heterobimetallic metal-organic framework cyanosilylation hydroboration yttrium europium Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n (in advance, namely Y/Eu-MOF), is described. The three-dimensional structure has been synthesized by solvothermal routes and thoroughly characterized, by means of single crystal X-ray diffraction, powder X-ray diffraction, electronic microscopy, ICP-AES, electrophoretic mobility, and FTIR spectra. Intriguingly, the porous nature allows for coordinated solvent molecules displacement, yielding unsaturated metal centers, which can act as a Lewis acid catalyst. This novel supramolecular entity has been tested in cyanosilylation and hydroboration reactions on carbonyl substrates of a diverse nature, exhibiting an extraordinary activity. 2022-03-10T18:08:44Z 2022-03-10T18:08:44Z 2022-03-06 info:eu-repo/semantics/article 2073-4344 http://hdl.handle.net/10835/13440 10.3390/catal12030299 en https://www.mdpi.com/2073-4344/12/3/299 Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess MDPI |
| spellingShingle | heterobimetallic metal-organic framework cyanosilylation hydroboration yttrium europium Echenique-Errandonea, Estitxu López-Vargas, Mireya E. Pérez, Juana M. Rojas, Sara Choquesillo-Lazarte, Duane Seco, José M. Fernández de las Nieves, Ignacio Rodríguez-Diéguez, Antonio A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls |
| title | A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls |
| title_full | A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls |
| title_fullStr | A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls |
| title_full_unstemmed | A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls |
| title_short | A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls |
| title_sort | mixed heterobimetallic y/eu-mof for the cyanosilylation and hydroboration of carbonyls |
| topic | heterobimetallic metal-organic framework cyanosilylation hydroboration yttrium europium |
| url | http://hdl.handle.net/10835/13440 |
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