Thermal behaviour of the different parts of almond shells as waste biomass

The main aim of this study is to investigate the thermal behaviour of the different parts of almond shells produced in an almond industry as a waste biomass. For this purpose, several experiments have been conducted under laboratory conditions. After removing the mature almonds, the waste raw materi...

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Main Authors: Garzón Garzón, Eduardo, Arce, Carolina, Callejón Ferre, Ángel Jesús, Pérez Falcón, JM, Sánchez Soto, Pedro José
Format: info:eu-repo/semantics/article
Language:English
Published: 2023
Subjects:
Online Access:http://hdl.handle.net/10835/14811
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author Garzón Garzón, Eduardo
Arce, Carolina
Callejón Ferre, Ángel Jesús
Pérez Falcón, JM
Sánchez Soto, Pedro José
author_facet Garzón Garzón, Eduardo
Arce, Carolina
Callejón Ferre, Ángel Jesús
Pérez Falcón, JM
Sánchez Soto, Pedro José
author_sort Garzón Garzón, Eduardo
collection DSpace
description The main aim of this study is to investigate the thermal behaviour of the different parts of almond shells produced in an almond industry as a waste biomass. For this purpose, several experiments have been conducted under laboratory conditions. After removing the mature almonds, the waste raw materials subject of this study were treated with distilled water (10 min) and separated in several parts. Taking into account their physical characteristics, they were: (a) complete shells: exocarp, mesocarp and endocarp without grinding (Sample C); (b) ground samples of complete shells, sieved under 0.2 mm (Sample M); (c) hard layers of the endocarp (Sample E); (d) internal layers of the endocarp (Sample I); and (e) mature drupes (Sample P) or skin, being constituted by the flexible part of green colour (fresh form) or yellow (after drying). The thermal behaviour of all these sample materials has been investigated using a laboratory furnace, with determination of ash contents and mass loss by progressive heating (120 min of holding time). Elemental and DTA-TG/DTG analyses of selected sample materials have been carried out. Although a complete study can be very complex, a first approach has been performed in this investigation. Results on thermal decomposition of this biomass waste have been presented to emphasize the main differences between sample materials of almond shells. These results have demonstrated the influence of several parameters, such as the particle size, and previous treatments in the thermal behaviour of the different parts of the almond shells, as showed in this investigation. Structural analysis of almond shells allowed to determine lignin, cellulose and hemicellulose. From the lignin content, it has been predicted the higher heating value (18.24 MJkg(-1)) of this waste as by-product of industrial interest. Other linear correlations to calculate this parameter have been applied with similar results in all these samples.
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spelling oai:repositorio.ual.es:10835-148112023-12-15T11:45:16Z Thermal behaviour of the different parts of almond shells as waste biomass Garzón Garzón, Eduardo Arce, Carolina Callejón Ferre, Ángel Jesús Pérez Falcón, JM Sánchez Soto, Pedro José Almond shells Biomass Thermal behaviour Wastes Lignin Higher heating value The main aim of this study is to investigate the thermal behaviour of the different parts of almond shells produced in an almond industry as a waste biomass. For this purpose, several experiments have been conducted under laboratory conditions. After removing the mature almonds, the waste raw materials subject of this study were treated with distilled water (10 min) and separated in several parts. Taking into account their physical characteristics, they were: (a) complete shells: exocarp, mesocarp and endocarp without grinding (Sample C); (b) ground samples of complete shells, sieved under 0.2 mm (Sample M); (c) hard layers of the endocarp (Sample E); (d) internal layers of the endocarp (Sample I); and (e) mature drupes (Sample P) or skin, being constituted by the flexible part of green colour (fresh form) or yellow (after drying). The thermal behaviour of all these sample materials has been investigated using a laboratory furnace, with determination of ash contents and mass loss by progressive heating (120 min of holding time). Elemental and DTA-TG/DTG analyses of selected sample materials have been carried out. Although a complete study can be very complex, a first approach has been performed in this investigation. Results on thermal decomposition of this biomass waste have been presented to emphasize the main differences between sample materials of almond shells. These results have demonstrated the influence of several parameters, such as the particle size, and previous treatments in the thermal behaviour of the different parts of the almond shells, as showed in this investigation. Structural analysis of almond shells allowed to determine lignin, cellulose and hemicellulose. From the lignin content, it has been predicted the higher heating value (18.24 MJkg(-1)) of this waste as by-product of industrial interest. Other linear correlations to calculate this parameter have been applied with similar results in all these samples. 2023-12-15T11:45:16Z 2023-12-15T11:45:16Z 2021-06-20 info:eu-repo/semantics/article 1388-6150 http://hdl.handle.net/10835/14811 en https://doi.org/10.1007/s10973-021-10940-x Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess
spellingShingle Almond shells
Biomass
Thermal behaviour
Wastes
Lignin
Higher heating value
Garzón Garzón, Eduardo
Arce, Carolina
Callejón Ferre, Ángel Jesús
Pérez Falcón, JM
Sánchez Soto, Pedro José
Thermal behaviour of the different parts of almond shells as waste biomass
title Thermal behaviour of the different parts of almond shells as waste biomass
title_full Thermal behaviour of the different parts of almond shells as waste biomass
title_fullStr Thermal behaviour of the different parts of almond shells as waste biomass
title_full_unstemmed Thermal behaviour of the different parts of almond shells as waste biomass
title_short Thermal behaviour of the different parts of almond shells as waste biomass
title_sort thermal behaviour of the different parts of almond shells as waste biomass
topic Almond shells
Biomass
Thermal behaviour
Wastes
Lignin
Higher heating value
url http://hdl.handle.net/10835/14811
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