First exfoliated Ru–Ru–Au organometallic polymer with layered structure.
A new water soluble heterometallic polymeric complex [{(PTA)2 CpRu-l-CN-1jC:2j2N-RuCp(PTA)2}-l-{Au(CN)4}4]n 2H2O (1) is synthesized and characterized by single crystal X-ray diffraction. This complex self-assembles forming 3D polymeric structures with large scale hexagonal conformation. They als...
| Main Authors: | , , , , |
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| Format: | info:eu-repo/semantics/article |
| Language: | English |
| Published: |
2024
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| Subjects: | |
| Online Access: | http://hdl.handle.net/10835/15048 |
| _version_ | 1789406493156573184 |
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| author | Scalambra, Franco Serrano Ruiz, Manuel Sierra Martín, Benjamín Fernández Barbero, Antonio José Romerosa Nievas, Antonio Manuel |
| author_facet | Scalambra, Franco Serrano Ruiz, Manuel Sierra Martín, Benjamín Fernández Barbero, Antonio José Romerosa Nievas, Antonio Manuel |
| author_sort | Scalambra, Franco |
| collection | DSpace |
| description | A new water soluble heterometallic polymeric complex [{(PTA)2
CpRu-l-CN-1jC:2j2N-RuCp(PTA)2}-l-{Au(CN)4}4]n 2H2O (1) is synthesized
and characterized by single crystal X-ray diffraction. This
complex self-assembles forming 3D polymeric structures with large
scale hexagonal conformation. They also organize as 3D stacks of
polymer sandwiches that can be exfoliated providing mono
heterometallic-3D layers, as shown by electron microscopy.
Regarding the polymer dynamics, quasi-elastic neutron scattering
shows a transition from vibrational Debye–Waller behaviour to a
more dynamically active state as a result of the loss of structural
water molecules. |
| format | info:eu-repo/semantics/article |
| id | oai:repositorio.ual.es:10835-15048 |
| institution | Universidad de Cuenca |
| language | English |
| publishDate | 2024 |
| record_format | dspace |
| spelling | oai:repositorio.ual.es:10835-150482024-01-10T09:16:35Z First exfoliated Ru–Ru–Au organometallic polymer with layered structure. Scalambra, Franco Serrano Ruiz, Manuel Sierra Martín, Benjamín Fernández Barbero, Antonio José Romerosa Nievas, Antonio Manuel organometallic polymer A new water soluble heterometallic polymeric complex [{(PTA)2 CpRu-l-CN-1jC:2j2N-RuCp(PTA)2}-l-{Au(CN)4}4]n 2H2O (1) is synthesized and characterized by single crystal X-ray diffraction. This complex self-assembles forming 3D polymeric structures with large scale hexagonal conformation. They also organize as 3D stacks of polymer sandwiches that can be exfoliated providing mono heterometallic-3D layers, as shown by electron microscopy. Regarding the polymer dynamics, quasi-elastic neutron scattering shows a transition from vibrational Debye–Waller behaviour to a more dynamically active state as a result of the loss of structural water molecules. 2024-01-10T09:16:34Z 2024-01-10T09:16:34Z 2020 info:eu-repo/semantics/article http://hdl.handle.net/10835/15048 en Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Chemical Communication, 2020, 56, 9441-9444. DOI: 10.1039/d0cc04325g |
| spellingShingle | organometallic polymer Scalambra, Franco Serrano Ruiz, Manuel Sierra Martín, Benjamín Fernández Barbero, Antonio José Romerosa Nievas, Antonio Manuel First exfoliated Ru–Ru–Au organometallic polymer with layered structure. |
| title | First exfoliated Ru–Ru–Au organometallic polymer with layered structure. |
| title_full | First exfoliated Ru–Ru–Au organometallic polymer with layered structure. |
| title_fullStr | First exfoliated Ru–Ru–Au organometallic polymer with layered structure. |
| title_full_unstemmed | First exfoliated Ru–Ru–Au organometallic polymer with layered structure. |
| title_short | First exfoliated Ru–Ru–Au organometallic polymer with layered structure. |
| title_sort | first exfoliated ru–ru–au organometallic polymer with layered structure. |
| topic | organometallic polymer |
| url | http://hdl.handle.net/10835/15048 |
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