Steps ahead in understanding the catalytic isomerization mechanism of linear allylic alcohols in water: dynamics, bonding analysis and crystal structure of a 2-allyl-intermediate.

Steps ahead in understanding the catalytic isomerization mechanism of linear allylic alcohols in water: dynamics, bonding analysis and crystal structure of a 2-allyl-intermediate.

The isomerization of 1-penten-3-ol into 3-pentanone catalyzed by [RuCp(H2O-κO)(PTA)2](CF3SO3) (1CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) was studied and two watersoluble ruthenium catalyst reaction intermediates were characterized. The main intermediate, the complex [RuCp(exo-η2-1-penten...

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Bibliographic Details
Main Authors: Scalambra, Franco, López-Sánchez, Belen, Holzmann, Nicole, Bernasconi, Leonardo, Romerosa Nievas, Antonio Manuel
Format: info:eu-repo/semantics/article
Language:English
Published: 2024
Subjects:
Alcohols
Crystal structure
Isomerization
Ligands
Molecular structure
Online Access:http://hdl.handle.net/10835/15049

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