Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution.
Neutron scattering combined with ab initio calculations provides a powerful tool for studying metal complexes in different solvents and, particularly, in water. The majority of traditional characterization techniques in catalysis provide only limited information on homogeneous catalytic processe...
| Main Authors: | , , , , |
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| Format: | info:eu-repo/semantics/article |
| Language: | English |
| Published: |
2024
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| Subjects: | |
| Online Access: | http://hdl.handle.net/10835/15050 |
| _version_ | 1789406342420627456 |
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| author | Scalambra, Franco Imberti, Silvia Holzmann, Nicole Bernasconi, Leonardo Romerosa Nievas, Antonio Manuel |
| author_facet | Scalambra, Franco Imberti, Silvia Holzmann, Nicole Bernasconi, Leonardo Romerosa Nievas, Antonio Manuel |
| author_sort | Scalambra, Franco |
| collection | DSpace |
| description | Neutron scattering combined with ab initio
calculations provides a powerful tool for studying metal complexes
in different solvents and, particularly, in water. The majority of
traditional characterization techniques in catalysis provide only
limited information on homogeneous catalytic processes. Neutron
scattering, on the other hand, thanks to its sensitivity to hydrogen
atoms, and therefore water molecules, can be used to build detailed
models of reaction paths and to observe, at a molecular level, the
influence of solvent molecules on a catalytic process. In this Mini-
Review we describe several examples on how neutron scattering
combined with ab initio calculations can be used to examine the
nature of the interaction of water molecules with catalytically active
metal complexes in solution. |
| format | info:eu-repo/semantics/article |
| id | oai:repositorio.ual.es:10835-15050 |
| institution | Universidad de Cuenca |
| language | English |
| publishDate | 2024 |
| record_format | dspace |
| spelling | oai:repositorio.ual.es:10835-150502024-01-10T09:37:02Z Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. Scalambra, Franco Imberti, Silvia Holzmann, Nicole Bernasconi, Leonardo Romerosa Nievas, Antonio Manuel Neutron Scattering Techniques Studying Metal Complexes Aqueous Solution Neutron scattering combined with ab initio calculations provides a powerful tool for studying metal complexes in different solvents and, particularly, in water. The majority of traditional characterization techniques in catalysis provide only limited information on homogeneous catalytic processes. Neutron scattering, on the other hand, thanks to its sensitivity to hydrogen atoms, and therefore water molecules, can be used to build detailed models of reaction paths and to observe, at a molecular level, the influence of solvent molecules on a catalytic process. In this Mini- Review we describe several examples on how neutron scattering combined with ab initio calculations can be used to examine the nature of the interaction of water molecules with catalytically active metal complexes in solution. 2024-01-10T09:37:02Z 2024-01-10T09:37:02Z 2021 info:eu-repo/semantics/article http://hdl.handle.net/10835/15050 en Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess ACS Omega 2021, 6, 1751−1757, DOI: https://doi.org/10.1021/acsomega.0c05030 |
| spellingShingle | Neutron Scattering Techniques Studying Metal Complexes Aqueous Solution Scalambra, Franco Imberti, Silvia Holzmann, Nicole Bernasconi, Leonardo Romerosa Nievas, Antonio Manuel Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. |
| title | Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. |
| title_full | Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. |
| title_fullStr | Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. |
| title_full_unstemmed | Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. |
| title_short | Neutron Scattering Techniques for Studying Metal Complexes in Aqueous Solution. |
| title_sort | neutron scattering techniques for studying metal complexes in aqueous solution. |
| topic | Neutron Scattering Techniques Studying Metal Complexes Aqueous Solution |
| url | http://hdl.handle.net/10835/15050 |
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