Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5]
A new RuII–ReII complex salt, -cyanido- 2C:N-bis[( 5-cyclopentadienyl)bis- (3,5,7-triazaphosphaadamantane- P)ruthenium(II)] tetrabromido(ethanol/ methanol- O)nitrosylrhenate(II), [Ru(CN)(C5H5)2(C6H12N3P)4][ReBr4(NO)- (CH4O)0.5(C2H6O)0.5] or [RuCp(PTA)2– -CN–1 C:2 2N-RuCp(PTA)2]- [Re(NO)Br4(EtOH...
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| Format: | info:eu-repo/semantics/article |
| Language: | English |
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2024
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| Online Access: | http://hdl.handle.net/10835/15055 |
| _version_ | 1789406639082700800 |
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| author | Pacheco, Mario Alvarez, Natalia Cuevas, Alicia Romerosa Nievas, Antonio Manuel Lloret, Francesc Kremer, Carlos |
| author_facet | Pacheco, Mario Alvarez, Natalia Cuevas, Alicia Romerosa Nievas, Antonio Manuel Lloret, Francesc Kremer, Carlos |
| author_sort | Pacheco, Mario |
| collection | DSpace |
| description | A new RuII–ReII complex salt, -cyanido- 2C:N-bis[( 5-cyclopentadienyl)bis-
(3,5,7-triazaphosphaadamantane- P)ruthenium(II)] tetrabromido(ethanol/
methanol- O)nitrosylrhenate(II), [Ru(CN)(C5H5)2(C6H12N3P)4][ReBr4(NO)-
(CH4O)0.5(C2H6O)0.5] or [RuCp(PTA)2– -CN–1 C:2 2N-RuCp(PTA)2]-
[Re(NO)Br4(EtOH)0.5(MeOH)0.5] (PTA = 3,5,7-triazaphosphaadamantane)
was obtained and characterized by single-crystal X-ray diffraction, elemental
analysis and infrared spectroscopy. The title salt was obtained by liquid–liquid
diffusion of methanol/DMSO solutions of (NBu4)[Re(NO)Br4(EtOH)] and
[(PTA)2CpRu– -CN–1 C:2 2N-RuCp(PTA)2](CF3SO3). The RuII and ReII
independent moieties correspond to a binuclear and mononuclear complex
ion, respectively. A deep geometrical parameter analysis was performed, and no
significant differences were found with earlier reports containing similar
molecules. The magnetic properties were investigated in the temperature range
2.0–300 K, and the complex behaves as a quasi-magnetically isolated spin
doublet with weak antiferromagnetic interactions. |
| format | info:eu-repo/semantics/article |
| id | oai:repositorio.ual.es:10835-15055 |
| institution | Universidad de Cuenca |
| language | English |
| publishDate | 2024 |
| record_format | dspace |
| spelling | oai:repositorio.ual.es:10835-150552024-01-10T10:00:03Z Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] Pacheco, Mario Alvarez, Natalia Cuevas, Alicia Romerosa Nievas, Antonio Manuel Lloret, Francesc Kremer, Carlos X-ray structure ruthenium(II) rhenium(II) PTA magnetism crystal structure A new RuII–ReII complex salt, -cyanido- 2C:N-bis[( 5-cyclopentadienyl)bis- (3,5,7-triazaphosphaadamantane- P)ruthenium(II)] tetrabromido(ethanol/ methanol- O)nitrosylrhenate(II), [Ru(CN)(C5H5)2(C6H12N3P)4][ReBr4(NO)- (CH4O)0.5(C2H6O)0.5] or [RuCp(PTA)2– -CN–1 C:2 2N-RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] (PTA = 3,5,7-triazaphosphaadamantane) was obtained and characterized by single-crystal X-ray diffraction, elemental analysis and infrared spectroscopy. The title salt was obtained by liquid–liquid diffusion of methanol/DMSO solutions of (NBu4)[Re(NO)Br4(EtOH)] and [(PTA)2CpRu– -CN–1 C:2 2N-RuCp(PTA)2](CF3SO3). The RuII and ReII independent moieties correspond to a binuclear and mononuclear complex ion, respectively. A deep geometrical parameter analysis was performed, and no significant differences were found with earlier reports containing similar molecules. The magnetic properties were investigated in the temperature range 2.0–300 K, and the complex behaves as a quasi-magnetically isolated spin doublet with weak antiferromagnetic interactions. 2024-01-10T10:00:03Z 2024-01-10T10:00:03Z 2021 info:eu-repo/semantics/article http://hdl.handle.net/10835/15055 en Atribución-NoComercial-CompartirIgual 4.0 Internacional http://creativecommons.org/licenses/by-nc-sa/4.0/ info:eu-repo/semantics/openAccess Acta Crystallographica, Section E: Crystallographic Communications (2021), 77(7), 749-754, DOI: https://doi.org/10.1107/S2056989021006381 |
| spellingShingle | X-ray structure ruthenium(II) rhenium(II) PTA magnetism crystal structure Pacheco, Mario Alvarez, Natalia Cuevas, Alicia Romerosa Nievas, Antonio Manuel Lloret, Francesc Kremer, Carlos Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] |
| title | Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] |
| title_full | Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] |
| title_fullStr | Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] |
| title_full_unstemmed | Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] |
| title_short | Crystal structure and magnetic study of the complex salt [RuCp(PTA)2–-CN-1C:2N–RuCp(PTA)2]- [Re(NO)Br4(EtOH)0.5(MeOH)0.5] |
| title_sort | crystal structure and magnetic study of the complex salt [rucp(pta)2–-cn-1c:2n–rucp(pta)2]- [re(no)br4(etoh)0.5(meoh)0.5] |
| topic | X-ray structure ruthenium(II) rhenium(II) PTA magnetism crystal structure |
| url | http://hdl.handle.net/10835/15055 |
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