Metal free phosphorus butterfly compounds
Metal-free organophosphorus are demanded compounds due to their interesting properties in a variety of applications, spanning from fine to material chemistry. Unfortunately, their synthesis is very challenging, requiring a precise design of the reaction conditions to avoid the conspicuous format...
| Main Authors: | , |
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| Format: | info:eu-repo/semantics/article |
| Language: | English |
| Published: |
2024
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| Subjects: | |
| Online Access: | http://hdl.handle.net/10835/15056 |
| _version_ | 1789406762611245056 |
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| author | Scalambra, Franco Romerosa Nievas, Antonio Manuel |
| author_facet | Scalambra, Franco Romerosa Nievas, Antonio Manuel |
| author_sort | Scalambra, Franco |
| collection | DSpace |
| description | Metal-free organophosphorus are demanded compounds due
to their interesting properties in a variety of applications,
spanning from fine to material chemistry. Unfortunately, their
synthesis is very challenging, requiring a precise design of the
reaction conditions to avoid the conspicuous formation of
undesired products. The P-butterfly scaffold is considered the
very first opening step of the white phosphorus tetrahedron
upon selective cleavage of just one P P bond. While the
synthesis of metal-containing P-butterflies is nowadays reproducible
with a variety of transition metal complexes, the metalfree
analogues are still elusive and just a limited number of
examples is described in the literature. The state of art on
known metal-free phosphorus butterfly compounds is described
herein. |
| format | info:eu-repo/semantics/article |
| id | oai:repositorio.ual.es:10835-15056 |
| institution | Universidad de Cuenca |
| language | English |
| publishDate | 2024 |
| record_format | dspace |
| spelling | oai:repositorio.ual.es:10835-150562024-01-10T10:05:52Z Metal free phosphorus butterfly compounds Scalambra, Franco Romerosa Nievas, Antonio Manuel Metal-free organophosphorus Metal-free organophosphorus are demanded compounds due to their interesting properties in a variety of applications, spanning from fine to material chemistry. Unfortunately, their synthesis is very challenging, requiring a precise design of the reaction conditions to avoid the conspicuous formation of undesired products. The P-butterfly scaffold is considered the very first opening step of the white phosphorus tetrahedron upon selective cleavage of just one P P bond. While the synthesis of metal-containing P-butterflies is nowadays reproducible with a variety of transition metal complexes, the metalfree analogues are still elusive and just a limited number of examples is described in the literature. The state of art on known metal-free phosphorus butterfly compounds is described herein. 2024-01-10T10:05:52Z 2024-01-10T10:05:52Z 2021 info:eu-repo/semantics/article http://hdl.handle.net/10835/15056 en Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess European Journal of Inorganic Chemistry, 2021, 291–298, DOI: https://doi.org/10.1002/ejic.202000923 |
| spellingShingle | Metal-free organophosphorus Scalambra, Franco Romerosa Nievas, Antonio Manuel Metal free phosphorus butterfly compounds |
| title | Metal free phosphorus butterfly compounds |
| title_full | Metal free phosphorus butterfly compounds |
| title_fullStr | Metal free phosphorus butterfly compounds |
| title_full_unstemmed | Metal free phosphorus butterfly compounds |
| title_short | Metal free phosphorus butterfly compounds |
| title_sort | metal free phosphorus butterfly compounds |
| topic | Metal-free organophosphorus |
| url | http://hdl.handle.net/10835/15056 |
| work_keys_str_mv | AT scalambrafranco metalfreephosphorusbutterflycompounds AT romerosanievasantoniomanuel metalfreephosphorusbutterflycompounds |