Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils

The characterization of the content of trace metals in soils is an instrument in many programs of environmental protection, including the establishment of regional-level standards to detect sites affected by contamination. The objectives of the present study were to study the available levels of Cd,...

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Main Authors: Rato Nunes, José, Ramos Miras, José Joaquín, Lopez Piñeiro, António, Loures, Luís, Gil De Carrasco, Carlos, Coelho, José, Loures, Ana
Format: info:eu-repo/semantics/article
Language:English
Published: MDPI 2020
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Online Access:http://hdl.handle.net/10835/7386
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author Rato Nunes, José
Ramos Miras, José Joaquín
Lopez Piñeiro, António
Loures, Luís
Gil De Carrasco, Carlos
Coelho, José
Loures, Ana
author_facet Rato Nunes, José
Ramos Miras, José Joaquín
Lopez Piñeiro, António
Loures, Luís
Gil De Carrasco, Carlos
Coelho, José
Loures, Ana
author_sort Rato Nunes, José
collection DSpace
description The characterization of the content of trace metals in soils is an instrument in many programs of environmental protection, including the establishment of regional-level standards to detect sites affected by contamination. The objectives of the present study were to study the available levels of Cd, Cr, Cu, Ni, Pb, and Zn in surface horizons of agricultural soils in a typical European Mediterranean region, to establish the geochemical baseline concentration (GBC), background level (BL), and reference value (RV) of each of these available metals, and to investigate their possible correlations with soil properties. To establish the GBC and RV values, we used the “standard threshold method”. Topsoil samples (0–20 cm) were collected from 630 sites, and extracted with Diethylene Triamine Pentaacetic Acid (DTPA) to determine their available heavy metal concentrations. The GBC values established were: 0.04 to 0.90 mg kg−1, 0.70 to 2.50 mg kg−1, 0.10 to 6.30 mg kg−1, 0.30 to 7.90 mg kg−1, 0.29 to 4.50 mg kg−1, and 0.18 to 2.50 mg kg−1 for Cd, Cr, Cu, Ni, Pb, and Zn, respectively. Soil properties were found to be correlated with the available heavy metal content, suggesting that the enhanced mobility of heavy metals are related to anthropic activities.
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spelling oai:repositorio.ual.es:10835-73862023-04-12T18:55:36Z Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils Rato Nunes, José Ramos Miras, José Joaquín Lopez Piñeiro, António Loures, Luís Gil De Carrasco, Carlos Coelho, José Loures, Ana available heavy metals Mediterranean agricultural soils DTPA geochemical baseline concentrations reference values The characterization of the content of trace metals in soils is an instrument in many programs of environmental protection, including the establishment of regional-level standards to detect sites affected by contamination. The objectives of the present study were to study the available levels of Cd, Cr, Cu, Ni, Pb, and Zn in surface horizons of agricultural soils in a typical European Mediterranean region, to establish the geochemical baseline concentration (GBC), background level (BL), and reference value (RV) of each of these available metals, and to investigate their possible correlations with soil properties. To establish the GBC and RV values, we used the “standard threshold method”. Topsoil samples (0–20 cm) were collected from 630 sites, and extracted with Diethylene Triamine Pentaacetic Acid (DTPA) to determine their available heavy metal concentrations. The GBC values established were: 0.04 to 0.90 mg kg−1, 0.70 to 2.50 mg kg−1, 0.10 to 6.30 mg kg−1, 0.30 to 7.90 mg kg−1, 0.29 to 4.50 mg kg−1, and 0.18 to 2.50 mg kg−1 for Cd, Cr, Cu, Ni, Pb, and Zn, respectively. Soil properties were found to be correlated with the available heavy metal content, suggesting that the enhanced mobility of heavy metals are related to anthropic activities. 2020-01-16T11:35:35Z 2020-01-16T11:35:35Z 2014-12-09 info:eu-repo/semantics/article 2071-1050 http://hdl.handle.net/10835/7386 en https://www.mdpi.com/2071-1050/6/12/9124 Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess MDPI
spellingShingle available heavy metals
Mediterranean agricultural soils
DTPA
geochemical baseline concentrations
reference values
Rato Nunes, José
Ramos Miras, José Joaquín
Lopez Piñeiro, António
Loures, Luís
Gil De Carrasco, Carlos
Coelho, José
Loures, Ana
Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils
title Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils
title_full Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils
title_fullStr Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils
title_full_unstemmed Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils
title_short Concentrations of Available Heavy Metals in Mediterranean Agricultural Soils and their Relation with Some Soil Selected Properties: A Case Study in Typical Mediterranean Soils
title_sort concentrations of available heavy metals in mediterranean agricultural soils and their relation with some soil selected properties: a case study in typical mediterranean soils
topic available heavy metals
Mediterranean agricultural soils
DTPA
geochemical baseline concentrations
reference values
url http://hdl.handle.net/10835/7386
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