The half-sandwich titanocene CpTiIIICl2 as efficient system for the preparation of 2,5-dihydrofurans via α-allenols

The half-sandwich titanocene CpTiIIICl2 as efficient system for the preparation of 2,5-dihydrofurans via α-allenols

The half-sandwich titanocene reagent CpTiIIICl2, obtained by in situ reduction of commercial CpTiCl3 with manganese, is an excellent system for the Barbier-type reaction between aldehydes and propargylic halides, leading to homopropargylic alcohols and α-allenols. An efficient and straightforward me...

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Bibliographic Details
Main Authors: Torres García, Irene, López Martínez, Josefa Leticia, Martínez-Martínez, Raquel, Oltra, J. Enrique, Muñoz Dorado, Manuel, Rodríguez García, Ignacio Manuel, Álvarez Corral, Míriam
Format: info:eu-repo/semantics/article
Language:English
Published: Wiley 2023
Subjects:
Organic Chemistry
Online Access:http://hdl.handle.net/10835/14794
https://doi.org/10.1002/aoc.5244

Internet

http://hdl.handle.net/10835/14794
https://doi.org/10.1002/aoc.5244

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